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Constropedia
Steel & Rebar

Chemical Composition of Reinforced Bar

Site tests on rebar usually stop at tensile and bend tests, so here is what each element in the steel does to strength, brittleness, weldability and corrosion resistance.

Objective and Significance

Conventional reinforced concrete is a composite material of reinforcing steel bars embedded in a hardened concrete matrix. The accurate information on the properties of the reinforcing steels as a construction material is important at the design or construction stage. There are many codes which specify the limits on the properties and testing procedures of the steel rebar. These are ASTM A615, BS4449, ISO 6935-2 etc. Reinforcing bar tests at most construction sites have been restricted to tensile and bend tests with little or no information about chemical composition as they relate to the structural performances of the bars.

Chemical composition variations in producing reinforcing steel bars are unavoidable. Carbon is the main strengthening element that participates in two strengthening mechanisms, solid solution and second phase formation (cementite). Although carbon increases the strength (mainly the tensile strength, TS) and the hardness, it decreases the ductility, in addition to affecting the weldability. The carbon equivalent represents the contribution of carbon and other elements to the formation of structures susceptible to hydrogen embrittlement during welding. Other properties of the rebar are compromised when the carbon steel with medium carbon content is used for fabricating rebar.

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Influence of different chemical ingredients in steel on properties of rebars

  1. Carbon (C): Higher carbon contributes to the tensile strength of steel, that is, higher load bearing capacity and vice versa. Lower carbon content less than 0.1 percent will reduce the strength. Higher carbon content of 0.3 percent and above makes the steel bar unweldable and brittle.
  2. Manganese (Mn): Higher manganese content in steel increases the tensile strength and also the carbon equivalent property.
  3. Sulphur (S): Presence of sulphur should be limited. Presence of higher sulphur makes the bar brittle during twisting, as higher sulphur content brings the hot shortness problem during rolling.
  4. Phosphorus (P): Higher phosphorus content contributes to the increase in strength and corrosion resistance properties but brings brittleness due to the formation of low euctoid phosphicles in the grain boundary. Also lowers the impact value at subzero temperature level (transition temperature).
  5. Copper (Cu): Being a pearlite stabiliser, it increases the strength and corrosion resistance property.
  6. Chromium (Cr): Present as an impurity from the scrap and influences carbon equivalent and weldability, and increases corrosion resistance property.
  7. Carbon Equivalent (CE or Ceq): This property is required to set the cooling parameters in TMT (Thermo mechanically treated) process and a slight variation in carbon equivalent may alter the physical properties. In case of CTD (Cold twisted deformed) bars, carbon equivalent has a maximum limit of 0.42 percent but there is no lower limit prescribed.

The chemical analysis of the steel is done in a certified lab and the results are reported as below.

Results

Blank rebar chemical analysis table: C, P, S, Cu, Cr, Mo, Ni, V, Si, Mn and CE columns; max, min, mean, SD and limit rows